MB I ordered has an aio connector thats 4 pin. can I...?
You tell us. You didn't even tell us the brand, let alone model number of the board.
Ruru is right. It depends on the specific board. So here's a concept that's, sadly, foreign to many - RTFM!
I frequently recommend to users of all experience levels (including myself), after selecting and ordering our parts, download the user manual and read it to become familiar with the layouts and features while we are waiting for the parts to be delivered. In many cases, it is wise to do this even BEFORE we have decided on which components we want to buy. This is nice if undecided as we may learn facts about one device that make it look more (or less) attractive than the competition - helping us to narrow down our options to the best choice for us.
So I recommend you download the user manual for this motherboard and see what the manufacturer says about that header, its capabilities and what it supports. Then do the rest of us a nice service and let us know what you have learned. That IS what forums are all about, after all, learning
and sharing what we have learned.
Note a side benefit to downloading the manual now is the on-line version is frequently updated/more current than the printed one in the box. In fact, a growing trend lately is to just include a "quick start" guide in the box with instructions to visit the site and download the full user guide.