P & E refers to the Performance cores and the Efficiency cores and the on chip cache that goes along with each of these cores.
The P & E voltages do not need to be synchronized with the main Core voltage and the P & E voltages do not need to be synchronized with each other.
I am not sure what CPU model you have. It looks like some sort of HX or K series CPU. There are other posts in this forum with offset voltage examples. Search Google for your CPU model..