i mean, would too much as5 result in not seeing much effect from the curing time, but the temps are quite fine in the first place
I recommend using more thermal paste when you do GPU than you would when you do the CPU. It is not like the CPU because there is no lid.
You want to make sure the entire die is radiating heat to the heatsink.
Try putting a small blob (pea sized) on the center of the die, putting your finger in a plastic sandwich bag and spreading the paste into a smooth, uniform, and thin layer.
Any excess paste will squeeze out the sides just like it does in the factory. If you use non conductive paste its extremely easy because you don't need to worry about the extra paste shorting out any circuits on the sides.
AS5 worked really well for me but you need to be slightly more careful about excess due to the conductivity. My 7850 has been running cool for 2.5 years now with AS5.
Once you get the machine booted up check the idle temperature. If its nice and low, run 3DMark or Unigen Valley/Heaven and make sure it stays within the recommended temperatures (usually well under 85*C) and doesn't artifact. If this all works out then play some games and if its still stable and running well you probably installed the thermal paste correctly.