I wanted to chime in here and add that I purchased my current set of RAM in July of last year. It's G.Skill Trident Z5 Neo, part number F5-6000J3636F16GX2-TZ5NR. I bought the kit alongside an X670E Hero board. No matter what I did, the kit absolutely would not POST when any EXPO profile (on ASUS there's EXPO I, EXPO II, and EXPO Tweaked) was active, even though the RAM was on the QVL (which, I know, means very little in all honesty), but would boot up just fine when EXPO was disabled. I returned that board and got the X670E Aorus Master from Gigabyte. Now, oddly enough, that board was able to POST with EXPO enabled without issue. But other problems cropped up recently, and I was very recently forced to replace my board.
I'm back on ASUS now - reluctantly, given all the crap they've been pulling in recent months - this time I'm on an Strix X670E-A. When I got it, I promptly updated the BIOS to the newest version (as it came with BIOS from 2023) 2308. Getting my RAM to post with EXPO enabled has largely been hit or miss in the couple weeks I've had this board. I've tried stuff I found on reddit from people having the same issues, but didn't feel very comfortable tweaking certain things (and I'm still not), and while one thing worked (can't remember which one it was) one day, the next day it wouldn't and I'd have to use the RAMs default speed if I wanted it to POST successfully. I'm honestly not sure anymore if my RAM is faulty (to my knowledge, that kit is Samsung-based) or just doesn't play nice with ASUS boards given that the Master had no problems POSTing with EXPO enabled.