It's kinda hard to hit 75C edge temp (GPU temp) on a reasonably sized 4070 Ti. You have to try pretty hard with shitty airflow. The current gen of GDDR6X runs pretty cool with even minimal effort to cool it with a baseplate, compared to RTX 30 series. ProArt looks pretty capable and big.
I'd let it run and keep an eye on HWinfo and confirm there actually is a problem (VRAM >90C or delta >20C) before opening it up. Asus is not known to be kind in any warranty and RMA matters - even in jurisdictions where Warranty Void stickers are illegal, it doesn't mean that Asus is not going to find other ways to screw you over.
Hotspot is impossible to predict. Every single sample of the same card is different. <10C delta is outstanding, +10C delta from edge temp is excellent (I'm at about 9-11), +15C is pretty common and +20C is on the edge of acceptable. More complex Radeon dies can get up to 25C delta without there being any real problem.
At the end of the day, replacing pads would do absolutely nothing to help your edge temp to hotspot temp delta - both are tied to AD104 and neither have anything to do with VRAM packages.
I was looking for any information on people with an Asus 4070 TI Tuf Gaming OC and found this thread and your reply. I have been using mine for 6 months.
My 4070 TI is in a Corsair 5000D with plenty of airflow and an ambient room temp of 21°C. The first 5 months it has been fantastic with a max GPU temp of 65C, memory at 62C and a hotspot of 80C when pulling 290w giving a delta of 15C.
However, over the last month, Temps have increased significantly. At 280-290w load, I'm seeing 72C GPU, 68C memory and 93C hotspot for a delta of 21C. As I'm sure you know, this is due to pump-out.
I am unwilling to RMA my GPU over this. Asus RMA is a total crap-shoot with an emphasis on crap.
I have the new Kryonaut Kryosheet sitting on my desk waiting for me to install it. I do not plan on replacing the pads as the memory Temps are quite acceptable and have likely only crept up in temp due to the GPU increasing in temp. I'll do some basic load testing before and after and report back with my findings.
There are quite a few posts across media platforms of people choosing to repaste their 4070 TI's and seeing Temps drop to more acceptable levels. Whatever paste Asus is using is particularly susceptible to pump-out.