Overclocking
For overclocking, I have kept the same procedures that I used for Intel's 10th generation. I have left the "Gear" setting on auto for memory overclocking. Every board tested so far has used "Gear 2" when pushing past the 3600 MHz XMP speed for my Trident Z Neo kit.
The ASUS ROG Maximus XIII Extreme Glacial showed a fair bit of headroom for overclocking. I was able to achieve 5.2 GHz at 1.38 V core voltage on both my i9-10900K and i9-11900K samples.
Overclocking is largely limited by temperature because the Intel Core i9 processors will overpower any ambient cooling solution. Depending on settings, the system will either crash or severely drop frequency.
For memory overclocking, the ASUS ROG Maximus XIII Extreme Glacial did well, reaching 4000 MHz stable at XMP timings and voltages on my Trident Z Neo kit with both 10th and 11th Gen samples.