You can't have less temperature when zeroth law dictates otherwise.
It is not impossible. You just failed to understand the level of thermal transmittance in 1°C gradient between copper-copper vs 0.1°C gradient between copper-water is equal.
Equilibrium is always present. It just doesn't create more entropy when the temperatures are the same. Stop thinking you can alter physics.
You're way off the deep end here. To
reach the temperatures you claim (to maintain them you first need to reach them, after all) you need to dissipate sufficient thermal energy from your CPU to the water for it to heat up that much
without that energy being dissipated through the radiator. And a crucial factor here (which has been repeated many times before): thermal transfer increases in efficiency as thermal deltas increase. In other words, as your water heats up, it will absorb less heat from the CPU and dissipate more heat through the radiator. Which will
raise CPU temperatures (unless it throttles), meaning your CPU temperature will no longer be 80°C. For your equilibrium state to be reached - 80°C CPU, 79.8°C water - in a normal water loop, you'd need these factors:
a) A CPU that throttles at 80°C, and refuses to go higher, with a constant workload
b) ambient air at such a high temperature that it won't meaningfully absorb heat from the radiator despite the radiator
also necessarily being close to 80°C, as the water is that temperature and has a huge contact area with the radiator.
c) A sufficiently high output of thermal energy from the CPU even when throttled to maintain these temperatures over ambient losses (i.e. thermal transfer from the ambient air and into the rest of the PC, the walls, floor, ceiling, etc.).
This will never happen. These are not even remotely realistic conditions. Heat will always dissipate
somewhere, and even a 250W CPU isn't sufficient to heat any meaningful amount of surrounding matter to 80°C and keep it there.
Equilibrium is always present.
Also, that sentence right there? Either you're speaking of scales so vast as to be entirely irrelevant in this context (as in "Earth's water cycle is in equilibrium"), or you just don't understand what you're saying. Maintaining any type of equilibrium of anything like temperature is
really really hard. Why do you think we've invented thermostats? They exist to do the work of creating thermal equilibrium (and they generally fail pretty badly!).